MITE0000209

MITE0000210

MITE0000211

Reaction Information

Number of Known Reactions: 1

Reaction 1
reaction SMARTS
Description Stereoselective epoxidation of the olefin at C6-7 in the chaetoglobosin A biosynthesis
Tailoring
  • Monooxygenation
Database References No database crosslinks available
Evidence
  • Knock-out studies
References
Example 1
Metadata
  • Description: Epoxidation of prochaetoglobosin I (chaetoglobosin V) at C6-7 to prochaetoglobosin IV
  • Intermediate: True
Substrate 1 substrate SMILES
Product 1 product SMILES
Example 2
Metadata
  • Description: Epoxidation of cytoglobosin D at C6-7 to 20-dihydro-chaetoglobosin A
  • Intermediate: True
Substrate 1 substrate SMILES
Product 1 product SMILES
Example 3
Metadata
  • Description: Epoxidation of chaetoglobosin J at C6-7 to chaetoglobosin A
  • Intermediate: False
Substrate 1 substrate SMILES
Product 1 product SMILES

Enzyme Information

Accession IDMITE0000210
Entry StatusStatus: active
Enzyme NameCheE
Enzyme DescriptionCytochrome P450
Database References
Cofactors
  • Organic
    • Heme
  • Inorganic
    • Fe
References
Enzyme Visualization (AlphaFold-predicted)

Version 1 (2025-03-27)

Contributor(s)
Reviewer(s)
Comment "new entry"

Version 2 (2025-07-25)

Contributor(s)
  • Anonymous MITE contributor
Reviewer(s)
Comment "Added cofactor information"

Version 3 (2025-08-26)

Contributor(s)
  • Anonymous MITE contributor
Reviewer(s)
Comment "Homogenized enzyme descriptions"